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A Volkswagen driven by Enrico Stampone, 26, of Totowa, crossed over the center line into the southbound lane near mile post 102.5 around 7:15 a.m., New Jersey State Police said.
He collided with a Hyundai driven by a 43-year-old Budd Lake woman near the border of Andover Borough and Byram Township, police said.
Both were airlifted to Morristown Medical Center with serious injuries, police said.
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